What are the TPS of rubber antioxidants?

The TPs of rubber antioxidants have been observed in some studies under environmental conditions. As one of the widespread rubber antioxidants, amine antioxidants (PPDs: TMPPD, DPPD, 6PPD, and 6PPDTZ) could react with O 3 (in parts per billion volume levels) in the environment and produce PPD-quinone .

Which rubber antioxidants are used in China?

Amine antioxidants are the main rubber antioxidants produced and used in China, of which 6PPD and 2,2,4-Trimethyl-1,2-dihydroquinoline (TMQ, RD) have the highest production, accounting for more than 80% of the total amine antioxidants.

Are p phenylenediamine (PPD) antioxidants in recycled tire rubber products toxic?

Recently, roadway releases of N, N ′-substituted p -phenylenediamine (PPD) antioxidants and their transformation products (TPs) received significant attention due to the highly toxic 6PPD-quinone. However, the occurrence of PPDs and TPs in recycled tire rubber products remains uncharacterized.

Do Antioxidants improve the performance of rubber?

Conclusions and Future Perspectives Antioxidants are widely used to improve the performance of rubber, and their production, especially 6PPD, is annually maintained at a high level .

Are rubber antioxidants toxic?

(2) The toxic effects of rubber antioxidants and their TPs may be evaluated via computational toxicology combined with traditional toxicological methods, including studies of short-term and sub-lethal exposure effects, the potential for mortality, mechanism of effect, and interaction with environmental variables.

Does antioxidant 2246 protect rubber from aging?

Among them, antioxidant 2246 has a good performance to protect rubber from aging caused by heat, oxygen, and metals. Because hydrogen in phenolic antioxidants can combine with the oxygen in air, their antiaging efficiency is therefore lowered compared with amine antioxidants [21, 22].