Are rubber antioxidants toxic?

(2) The toxic effects of rubber antioxidants and their TPs may be evaluated via computational toxicology combined with traditional toxicological methods, including studies of short-term and sub-lethal exposure effects, the potential for mortality, mechanism of effect, and interaction with environmental variables.

What are the TPS of rubber antioxidants?

The TPs of rubber antioxidants have been observed in some studies under environmental conditions. As one of the widespread rubber antioxidants, amine antioxidants (PPDs: TMPPD, DPPD, 6PPD, and 6PPDTZ) could react with O 3 (in parts per billion volume levels) in the environment and produce PPD-quinone .

What is the global consumption of rubber antioxidants?

To date, the annual global consumption of rubber antioxidants is over 700,000 tons, accounting for about 40% of the total amount of rubber additives. This is about twice higher than that of phosphorus flame retardants, a group of emerging pollutants which received great attention in the past decades .

Which rubber antioxidants are used in China?

Amine antioxidants are the main rubber antioxidants produced and used in China, of which 6PPD and 2,2,4-Trimethyl-1,2-dihydroquinoline (TMQ, RD) have the highest production, accounting for more than 80% of the total amine antioxidants.

What are amine antioxidants in rubber?

Amine antioxidant is the most common rubber antioxidant, which was produced as early as the 1970s and widely used in the rubber industry. Typical amine antioxidants include diaryl-secondary amine, acetone-amine condensation product, p -phenylenediamine, and aldehyde-amine condensation product antioxidants .

Why are chemical antioxidants used in rubber aging?

By contrast, chemical antioxidants are usually used to address the reaction stage of rubber aging. According to the different fracture modes of the molecular chain of raw rubber materials, different chemical antioxidants are added to block the growth reaction chain during aging .