Is acrylamide a self-healing copolymer?

In this study, a series of novel self-healing, high-strength copolymers of acrylamide, acrylic acid, and novel acrylic complexes of 4′-phenyl-2,2′:6′,2″-terpyridine [Co (II), Ni (II), and Cu (II)] was prepared.

Why were acrylamide and acrylic acid chosen as model copolymers?

Acrylamide and acrylic acid were chosen as model copolymers because the self-healing of their hydrogels is a frequent example of healing effects in polymers . The interaction of carboxyl and amide groups with metal ions also leads to the formation of self-healing metallopolymers .

What are polyacrylamide block copolymers used for?

Polyacrylamide block copolymers has been extensively used in many fields of science and technology due to their water solubility, biocompatibility and…

What is copper-catalyzed controlled polymerization of acrylamide?

Copper-catalyzed controlled polymerization of acrylamide (AM) has always been a challenge, which typically exhibits low monomer conversion and broad molecular weight distribution (MWD) or requires complex/multistep reaction procedures, due to the highly active nature of the AM radical and its side reactions.

What is the glass transition temperature of acrylamide & acrylic acid copolymers?

Typically, the glass transition temperature of acrylamide and acrylic acid copolymers ranges from ~97 °C, which is the Tg of pure polyacrylamide, to ~123 °C, which corresponds to the glass transition of polyacrylic acid [53, 54, 55].

How to control acrylamide polymerization?

To conclude, the controlled polymerizations of acrylamide have been successfully achieved via a one-pot and one-step aqueous Cu (0)-mediated RDRP approach. It has been demonstrated that strong deactivation control is the key for the control in AM RDRPs.