molecular understanding and structural-based design of ...

Molecular Understanding and Structural-Based Design of ...

This paper presents the design and synthesis of an amphoteric polyacrylamide. This polyampholyte was synthesized by polymerization in an aqueous solution. The characteristics of the functional group decide the properties of the polymer to a great extent [].

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thermo‐responsive polymer‐based nanoparticles: from chemical ...

Thermo‐Responsive Polymer‐Based Nanoparticles: From Chemical ...

SB-polymers were benchmarked against two linear polyacrylamides of comparable (entry 19) and higher (entry 20) molecular weight (as has been outlined earlier). The results of the simulations are summarized in Figure 7 ( M n is presented in Da for brevity), whereas the viscoelasticity measurements of the polymer solutions are displayed in Figure 8 .

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design and precise synthesis of thermoresponsive ...

Design and Precise Synthesis of Thermoresponsive ...

In this thesis, the author describes versatile and easy-to-use methods to control the properties of thermoresponsive polyacrylamides by developing novel synthetic methods for end-functionalized poly (N -isopropylacrylamide) (PNIPAM) and block copolymers of poly (N,N -diethylacrylamide) (PDEAA).

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molecular understanding and structural-based design of polya ...

Molecular Understanding and Structural-Based Design of Polya ...

Thermoresponsive properties of polyacrylamides in physiological Polymer Chemistry ( IF 5.582) Pub Date : 2021-08-13, DOI: 10.1039/d1py00843a Kristýna Kolouchová, Volodymyr Lobaz, Hynek Beneš, Victor R. de la Rosa, David Babuka, Pavel Švec, Peter Černoch, Martin Hrubý, Richard Hoogenboom, Petr Štěpánek, Ondřej Groborz

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amino-acid-derived anionic polyacrylamides with ... - acs ...

Amino-Acid-Derived Anionic Polyacrylamides with ... - ACS ...

Some aspects of the properties and degradation of polyacrylamides Chem Rev. 2002 Sep;102(9) :3067-84. doi: 10.1021/cr010439p ... Marcus J Caulfield 1 , Greg G Qiao, David H Solomon Affiliation 1 Polymer Science Group, Department of DOI: 10. ...

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 ... hydrophobically associating polyacrylamides and their partially ...

... Hydrophobically associating polyacrylamides and their partially ...

DOI: 10.1002/CHIN.200244274 Corpus ID: 197309086 Some Aspects of the Properties and Degradation of Polyacrylamides @article{Caulfield2002SomeAO, title={Some Aspects of the Properties and Degradation of Polyacrylamides}, author={Marcus J. Caulfield ...

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some aspects of the properties and degradation of polyacryla ...

Some Aspects of the Properties and Degradation of Polyacryla ...

Thermoresponsive properties of polyacrylamides in physiological solutions Polymer Chemistry ( IF 4.6) Pub Date : 2021-08-13, DOI: 10.1039/d1py00843a

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properties of hydrophobically associating polyacrylamides: i ...

Properties of hydrophobically associating polyacrylamides: i ...

have become the bottleneck of polymer flooding tech-nology in oil reservoirs [14,15], thus, it is urgent to research and develop novel polymers with good tem-perature-/salt- resistant properties. Zwitterionic polymers possessed equal numbers

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 ... adsorption properties of hydrophobically associating wa ...

... adsorption properties of hydrophobically associating wa ...

introduced polymer. In summary, the author developed new methods for the precise synthesis of polyacrylamides using the ATRP, the click reaction, and the GTP in order to con-trol the thermoresponsive properties of the polyacrylamides through the design of

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hydrophobically associating polyacrylamides modified by a ...

HYDROPHOBICALLY ASSOCIATING POLYACRYLAMIDES MODIFIED BY A ...

important role in determining the polymer conformation and its rheological properties in aqueous solutions[8, 9, 15−17]. Conventional micellar copolymerization systems require external surfactants which usually negatively affect the polymer properties such as

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molecular understanding and structural-based design of polya ...

Molecular Understanding and Structural-Based Design of Polya ...

Summary Polymer flooding is a widely used chemical technique used to enhance or speed up oil recovery from brown or green fields. Polyacrylamides used in chemical enhanced oil recovery processes can be supplied either in powder or inverse emulsion forms. The latter has several benefits for offshore deployment including smaller equipment footprint for dissolution and easier transportation to ...

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thermoresponsive properties of polyacrylamides in physiologi ...

Thermoresponsive properties of polyacrylamides in physiologi ...

Polymer solutions with a lower critical solution temperature (LCST) undergo reversible phase separation when heated above their cloud point temperature (T-CP or CPT). As such, the

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simple machine learning model for the glass transition ...

Simple machine learning model for the glass transition ...

Some aspects of the properties and degradation of polyacrylamides. Chemical Reviews ( IF 51.4 ) Pub Date : 2002-09-12 , DOI: 10.1021/cr010439p

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design of high-toughness polyacrylamide hydrogels by ...

Design of high-toughness polyacrylamide hydrogels by ...

Design of high-toughness polyacrylamide hydrogels by hydrophobic modification Suzan Abdurrahmanoglub, Volkan Cana, Oguz Okaya,* aIstanbul Technical University, Department of Chemistry, 34469 Maslak, Istanbul, Turkey b Marmara University, Department of Chemistry, Kadikoy, Istanbul, Turkey

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a library synthesis of highly isotactic polyacrylamides with ...

A Library Synthesis of Highly Isotactic Polyacrylamides with ...

Thermoresponsive polymers may require DLS for accurate T CP determination As shown in Fig. 3B, the T CP of pDFEA with the highest molar mass (F3) was much higher in PBS than in water. To understand the unexpected T CP of this polymer, as measured by turbidimetry, we assessed polymer aggregation as a function of temperature (10 to 50 C) by DLS, in PBS, at a concentration of 10.0 mg mL −1 (Fig ...

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How to control the properties of thermoresponsive polyacrylamides?

In this thesis, the author describes versatile and easy-to-use methods to control the properties of thermoresponsive polyacrylamides by developing novel synthetic methods for end-functionalized poly ( N -isopropylacrylamide) (PNIPAM) and block copolymers of poly ( N,N -diethylacrylamide) (PDEAA).

Why do polyacrylamides and polyacrylates have antifouling properties?

The strong surface hydration and the high surface packing density of polyacrylamides and polyacrylates are considered to be the key contributors to their antifouling property. In this article, we review our studies on the design and synthesis of a series of polyacrylamides and polyacrylates with different molecular structures.

Can polyacrylamide be used in high temperature applications?

Polyacrylamide has promising applications in a wide variety of fields. However, conventional polyacrylamide is prone to hydrolysis and thermal degradation under high temperature conditions, resulting in a decrease in solution viscosity with increasing temperature, which limits its practical effect.

Can poloxamers improve the stability and viscosity of nonionic polyacrylamide?

Subsequent rheological tests also showed that poloxamers can indeed significantly improve the stability and viscosity of nonionic polyacrylamide containing only amide groups at high temperatures and can maintain a high viscosity of 3550 mPa·S at 80 °C.

Can a poloxamer crosslinker improve thermal stability of polyacrylamide?

Herein, with the assistance of molecular dynamics simulations, we report a strategy to improve the thermal stability of polyacrylamide by using poloxamer as a crosslinker to form an interpenetrating network hydrogel.

What is polyacrylamide used for?

Polyacrylamide ( PAM ), a water-soluble material polymerized from acrylamide monomers [ 1, 2 ], is widely used in many fields, such as oil extraction, metallurgy, papermaking, and medicine [ 3, 4 ].