Is polyaluminium chloride better than polyelectrolyte – alum-based coagulation?

At the Barekese Water Treatment Plant in Ghana, an alternative, the polyelectrolyte – polyaluminium chloride (PAC) is also used in coagulation but limited information is available on the operating conditions required to achieve better performance than alum-based coagulation.

Does polyaluminum chloride coagulate with hydrolyzed coagulants?

Coagulation with hydrolyzing coagulants has been studied thoroughly, but the coagulation behavior of pre-hydrolyzed coagulants such as polyaluminum chloride (PACl), especially the coagulation mechanisms at various coagulant dosages and pH values of raw water, has not been systemically investigated and not been well understood , .

How PACL coagulation zones are compared with alum?

The coagulation zones at various PACl dosages and solution pH values were developed and compared with those of alum. It is found that the optimal mechanism under acidic condition is charge neutralization, while alkaline condition will facilitate the coagulation of PACl.

What is the optimal pH range for Pac coagulation?

The optimal pH range for PAC coagulation performance was 7.5 to 8.0. The coagulation process in conventional water treatment could be enhanced and the ensuing water pH decline reduced appreciably by applying the right dosage of polyaluminium chloride and appropriate process conditions of pH, fluid mixing speed matrix and residence time.

Do PACL precipitates control charge neutralization coagulation process?

The destabilization extent of primary particles and PACl precipitates seems to control charge neutralization coagulation process. Sufficient PACl precipitates could reduce the adverse effect of insufficient destabilization in charge neutralization coagulation process to some extent.

Is PACL a pre-hydrolyzed coagulant?

As a pre-hydrolyzed coagulant, PACl is becoming increasingly popular in the coagulation–flocculation process.