
Hydrophobically associating polyacrylamides and their ...
Polymers, such as partially hydrolyzed polyacrylamide (HPAM), are widely used in oil fields to enhance or improve the recovery of crude oil from the reservoirs. It works by increasing the viscosity of the injected water, thus improving its mobility and oil recovery.
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... Stability of Partially Hydrolyzed Polyacrylamides at Elevated ...
Summary At elevated temperatures in aqueous solution, partially hydrolyzed polyacrylamides (HPAMs) experience hydrolysis of amide side groups. However, in the absence of dissolved oxygen and divalent cations, the polymer backbone can remain stable so that HPAM solutions were projected to maintain at least half their original viscosity for more than 8 years at 100°C and for approximately 2 ...
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... Stability of Partially Hydrolyzed Polyacrylamides at Elevated ...
Report Objectives. In this report, we explore the temperature limits of stability to 180 C for HPAM polymer solutions if divalent cations and dissolved oxygen are not present. In general, we examine stability for HPAM solutions at higher temperatures than previous ...
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Stability of Partially Hydrolyzed Polyacrylamides at Elevate ...
SPE 121460 Stability of Partially Hydrolyzed Polyacrylamides at Elevated Temperatures in the Absence of Divalent Cations 3 Our work focused on two polymers. The first was SNF Flopaam 3830S , Lot R 2279. The manufacturer estimated the
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Stability of Partially Hydrolyzed Polyacrylamides at Elevate ...
June 2010 SPE Journal 341 Stability of Partially Hydrolyzed Polyacrylamides at Elevated Temperatures in the Absence of Divalent Cations R.S. Seright, SPE, A.R. Campbell, and P.S. Mozley, New Mexico Tech; and Peihui Han, SPE, Daqing Oilfi eld Company
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... Hydrophobically associating polyacrylamides and their partially ...
Abstract The partially hydrolyzed microblock hydrophobically associating polyacrylamides (HMBHAPs) with different microblock lengths (NH) and some positive charges were prepared by free radical copolymerization in aqueous solution and the HMBHAPs were ...
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Stability of Partially Hydrolyzed Polyacrylamides at Elevate ...
Supporting: 2, Mentioning: 64 - At elevated temperatures in aqueous solution, partially hydrolyzed polyacrylamides (HPAM) experience hydrolysis of amide side groups. However, in the absence of dissolved oxygen and divalent cations, the polymer backbone can remain stable so that HPAM solutions were projected to maintain at least half their original viscosity for over 7 years at 100°C and about ...
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Stability of Partially Hydrolyzed Polyacrylamides at Elevate ...
Report Objectives. In this report, we explore the temperature limits of stability to 180 C for HPAM polymer solutions if divalent cations and dissolved oxygen are not present. In general, we examine stability for HPAM solutions at higher temperatures than previous ...
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... Stability of Partially Hydrolyzed Polyacrylamides at Elevated ...
2009 SPE Journal 1 Stability of Partially Hydrolyzed Polyacrylamides at Elevated Temperatures in the Absence of Divalent Cations R.S. Seright, SPE, A.R. Campbell, and P.S. Mozley, New Mexico Tech; and Peihui Han, SPE, Daqing Oilfi eld Company, PetroChina
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Hydrolysis and Precipitation of Polyacrylamides in Hard Brin ...
Laboratory data are used to show that commercial polyacrylamides hydrolyze to an equilibrium degree that depends on the temperature of hydrolysis but is largely independent of the brine composition. At greater than 20 ppm hardness levels, polyacrylamide solutions pass through a sharp cloud point as their temperature is raised. This cloud-point temperature depends primarily on the hardness ...
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Statistical and rheological evaluation of the effect of ...
Partially hydrolyzed polyacrylamide (PHPA) is the most common anionic copolymer used in Enhanced oil recovery (EOR), but the use of this polymer presents some limitations in the presence of divalent cations. The objective of this work was to evaluate the Na+
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Insights on the Interaction between Sodium Dodecyl Sulfate ... 簡
Insights on the Interaction between Sodium Dodecyl Sulfate and Partially Hydrolyzed Microblock Hydrophobically Associating Polyacrylamides in Different Polymer Concentration Regimes Colloids and Surfaces A: Physicochemical and Engineering Aspects ( IF 5.2) Pub Date : 2019-07-01, DOI: 10.1016/j.colsurfa.2019.03.068
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Hydrophobically associating polyacrylamides and their partia ...
Abstract In high-temperature and high-salinity oil reservoirs, the poor thermal stability and salinity tolerance of partially hydrolyzed polyacrylamides (HPAM) solution hinder its efficiency in enhanced oil recovery (EOR). Therefore, a series of dispersible nano-SiO 2 ...
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Limiting conditions for the use of hydrolyzed polyacrylamide ...
This study summarizes the main parameters acting on the stability of hydrolyzed polyacrylamides in brines containing divalent ions. For dilute solutions the critical hydrolysis degree (CHD) above which the polymer may be precipitated by Ca ions is 35% at room temperature and 33% at 80/sup 0/C. For CHD less than 60%, the precipitated polymer redissolves at high CaCl/sub 2/ or NaCl ...
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Insights on the Interaction between Sodium Dodecyl Sulfate ...
Stability of partially hydrolyzed polyacrylamides at elevated temperatures in the absence of divalent cations RS Seright, AR Campbell, PS Mozley, P Han SPE journal 15 (02), 341-348, 2010 370 2010 Prediction of xanthan rheology in porous media WJ Cannella ...
Get PriceWhat is partially hydrolyzed polyacrylamide (HPAM)?
Partially hydrolyzed polyacrylamide (HPAM) was widely implemented to improve the rheological properties of displacing fluids, but the high temperature and salinity of the reservoir brine limited their applications.
Can nitrogen digestion determine the concentration of polyacrylamide-type polymers?
Conclusions The nitrogen digestion method is an effective way for determining the concentration of polyacrylamide-type polymers, including partially hydrolyzed polyacrylamide, sulfonated polyacrylamides, and cationic polyacrylamides.
What is the hydrolysis degree of polyacrylamide sulfonated polymer?
Using this alkaline post hydrolysis method, we obtained partially hydrolyzed polyacrylamides with hydrolysis degree of 45%, and 56% and hydrolyzed sulfonated polyacrylamides with hydrolysis degree of 9%, 10%, 13% and 17%. 2.7. Infrared (IR) spectra of polymers The drop preparation method was used in the IR analysis.
Does hydrolysis affect the nitrogen content of polyacrylamides?
Fig. 9 shows the variation of nitrogen content as a function of polymer concentration from 100 ppm to 1000 ppm of partially hydrolyzed polyacrylamides with the hydrolysis degrees of 30%, 45%, and 57%, respectively. Also, the experimental results show that the nitrogen contents of high HD polyacrylamides are lower than that of low HD ones.
What is the viscosity retention of polyacrylamide in pure water?
In pure water, the sample viscosity retention at 90 o C is about 38% of that value at 25 o C (Supplementary Figure S2D), which is comparable with the hydrophobically associating polyacrylamide under similar conditions (Zheng and Huang, 2019).
Are polyacrylamide-degrading bacterial strains isolated from soil?
Two polyacrylamide-degrading bacterial strains were isolated from soil, Bacillus sphaericus and Acinetobacter sp., utilizing 16–19% polyacrylamide after 14 days of cultivation (Matsuoka et al., 2002).
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