What is low molecular weight polyacrylamide?

Low molecular weight polyacrylamide was synthesized using hydrogen peroxide as initiator and the reaction was carried out at high temperature (90oC) to give polyacrylamide free of contaminates detected by FTIR spectroscopy. The product was a low viscosity white colour liquid.

Which polyacrylamide has the lowest stability?

On the other hand, very low molecular weight polyacrylamide displayed the lowest stability. The increase in molecular weight caused a decrease of weight loss %. The residue at 600oC being 11.67%, 14.68%, 17.83%, 19.45%, and 22.55% for the cases of very low, low, medium, high and very high molecular weight polyacrylamides respectively.

Does molecular weight affect thermal stability of polyacrylamide?

The very high molecular weight polyacrylamide displayed the highest stability in the series, indicating the importance of the molecular weight for thermal stability. On the other hand, very low molecular weight polyacrylamide displayed the lowest stability. The increase in molecular weight caused a decrease of weight loss %.

How to make high molecular weight polyacrylamide?

Thus, under nitrogen atmosphere 15, 30 and 50 gm of acrylamide monomer were polymerized in (500ml) distilled water as a solvent and the (0.135gm) potassium persulfate/(180μl) TEMDA system as initiator to produce medium, high and very high molecular weight polyacrylamides respectively.

Why do polyacrylamides lose weight?

Initially weight loss may arise from evaporation of residual moisture or solvent, but at higher temperatures it results from polymer decomposition (11). The thermal stability of the different molecular weight polyacrylamides has been studied by TGA from 50oC up to approximately 600oC.

How are polyacrylamides synthesized?

Abstract: Polyacrylamides of varying molecular weights (very low, low, medium, high and very high) were synthesized using free radical polymerization and characterized by Infra Red (IR) spectroscopy, viscosity measurements, glass transition temperature (Tg) measurement and thermal gravimetric analysis (TGA).