
Effect of Rubber Chemicals on the Surface Free Energy of NR ...
According to previous studies, the particle size, structure and surface activity of CB are the main factors that affect the reinforcement of rubber. In the chemical sense, the surface activity of CB depends on different chemical groups attached on the surface, such as carboxyl, hydroxyl, quinonyl and lactone [9].
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On factors affecting surface free energy of carbon black for ...
In this study, the effect of atmospheric DCSBD plasma mobile reactor on surface characteristics of un-vulcanized rubber blend surface, including surface structure, chemical composition, wettability, surface free energy, and adhesion have been estimated.
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Effect of surface free energy and wettability on the ...
In Chapter 5 the influence of polymer molecular weight, crosslink density and crosslinker functionality on PDMS rubber-rubber tack is described. These factors heavily influence the amount of loose chains, as well as their ability to entangle. The telechelic PDMS
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On factors affecting surface free energy of carbon black for ...
The surface activity of carbon black (CB) is an important factor affecting the reinforcement of rubber. The quantitative determination of the surface activity (surface free energy) of CB is of great significance. A simplified formula is obtained to determine the free energy of CB surface through theoretical analysis and mathematical derivation. The surface free energy for four kinds of ...
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Effect of the surface treatment of recycled rubber on the ...
<p>Various soft materials, e.g., papers, cloths, and sponges, can absorb water. In this study, we demonstrated the influence of the surface free energy of liquid and the liquid distribution on the friction behavior of a paper wiper on a glass plate. The friction test was performed by varying the liquid content in the paper wiper. Compared with the dry condition, the friction coefficient ...
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Comprehensive analysis of surface free energy of asphalts ...
The lubricating oil contamination of dental handpieces significantly reduces the adhesion between the CAD-CAM resin composite block and the resin composite. Therefore, it is necessary to remove contamination and improve the adhesiveness using an optimal chemical surface treatment.
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Effect of the silica-rubber interface on the mechanical, ...
effect of interfacial polymer–filler interactions on the final properties of the vulcanizates with the least interference from the chemical crosslink density.
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The effect of sandblasting on surface properties for adhesio ...
According to van Oss–Chaudhury–Good's theory, some key adhesion parameters (involving surface free energy, interfacial free energy, adhesion energy, and the spreading coefficient, etc.) of waterborne polyurethane (WPU) adhesives on shoe substrates, styrene–butadiene–styrene rubber (SBS), ethylene vinyl acetate (EVA), and polyvinyl chloride (PVC) were calculated and the relationships ...
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(PDF) Influences of Surface Free Energy on Rubber ... - Rese ...
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Get PriceWhy are rubber chemicals added to raw rubber?
Rubber chemicals are added to raw rubbers to improve their mechanical, environmental and processing properties. These chemicals often migrate to the surface and alter its free energy and ultimately its contact adhesion properties.
Does heat treatment affect the performance of rubber reinforced by CB?
The surface free energy (surface activity) is a major factor affecting the reinforcement of rubber. Therefore, it is important to further investigate the effect of heat treatment on the performance of the rubber reinforced by CB.
Can rubber chemicals be mixed with natural rubber?
In this study, some industrially important rubber chemicals were mixed with natural rubber and a blend of natural rubber and styrene-butadiene rubber, and the contact angle measured using drops of water and diiodomethane on the rubber surface.
How does surface free energy affect wear resistance?
With the increase of surface free energy, the maximum torque was decreased significantly, the elongation at break tended to increase, the heat generation of vulcanizates was increased, and the wear resistance was decreased. Keywords: carbon black; surface free energy; rubber
How does temperature affect the abrasion value of vulcanized rubber?
The results in Figure 14 show that the abrasion value of vulcanized rubber increases with the increase of temperature, which is due to the decrease of surface activity of CB particles, leading to the decrease of interaction between CB particles and rubber molecular chains. As a result, the wear resistance of vulcanized rubber decreased.
What ambivalent aspects influenced the CB–rubber interaction?
Above all, two ambivalent aspects influenced the CB–rubber interaction. One is the positive effect of AE on the formation of entanglement points, which improved the CB–rubber interaction. The other is the decrease of dispersive free energy ( γds) on the CB surface via adding AE that reduced the CB–rubber interaction.
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